Effects of multiple injections on the transport of CMC-nZVI in saturated sand columns

The multiple injections of nanoscale zero valent iron (nZVI) slurry, an efficient method to remediate contaminated groundwater, requires an accurate assessment of the transport and risks of these particles in saturated porous medium. However, the influencing mechanism of nZVI transport under multiple injection conditions is not fully understood. In this experimental study, one-dimensional sand columns were used to evaluate the effects of injection concentrations, particle sizes and surface chemical corrosion on the transport of carboxymethyl cellulose modified nZVI (CMC-nZVI) under triple injection conditions, where the different volumes of NaCl solution were flushed through the columns between the injections. Based on the breakthrough curves and retention profiles under flushing 4 pore volumes of NaCl solution between the injections, the transport of CMC-nZVI particles was gradually enhanced attributable to the exclusion among these particles at injection concentration of 200 mg/L, but the opposite was observed due to large aggregation caused by strong magnetic force among particles at 500 mg/L. However, the magnitudes of enhancement or reduction on maximum C/C₀ under the above injection concentrations were related to the smallest particle size of D_h = 3.926 μm because of high particle number concentrations leading to intense competition on depositional sites at 200 mg/L and significant aggregation at 500 mg/L. Conversely, the transport of CMC-nZVI was reduced under flushing 76 pore volumes of NaCl solution between the injections because of pronounced corrosion of CMC-nZVI in water as evidenced by the XPS and XRD analyses of particles. This corrosion could cause the decrease in repulsion among particles due to the increase in surface negative zeta potential and the CMC desorption from nZVI. Accordingly, this study revealed that relative high injection concentrations and chemical corrosion in groundwater could restrain the mobility of nZVI under multiple injection conditions and the potential risks posed by CMC-nZVI are controllable.