Advanced Acceptor-Substituted S,N-Heteropentacenes for Application in Organic Solar Cells
Teresa Kraus1, Sebastian Lucas1,2, Pascal Wolff1,2
1Institute of Organic Chemistry II and Advanced Materials, University of Ulm, Albert-Einstein-Allee 11, 89081, Ulm, Germany.
Abstract:
Ambifunctional heterpentacenes with the heteroatom sequence SSNSS in the ladder-type backbone were used either as donor or as nonfullerenic acceptor in solution-processed bulk-heterojunction solar cells. Different acceptor moieties and side chains were inserted. Synthesis and characterization of the systematically varied structural motifs provided insight in structure-property relationships. Moreover, a dimeric heteroacene was synthesized, and the optoelectronic properties were compared to those of its monomeric counterpart.
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