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A rechargeable aqueous proton battery based on a dipyridophenazine anode and an indium hexacyanoferrate cathode
Jun Qiao1, Meng Qin1, Yong-Miao Shen2
1Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University, Changzhou, 213164, China. jycao@cczu.edu.cn cjytion@cczu.com.
Abstract:
A rocking-chair aqueous proton battery is assembled by using dipyridophenazine and indium hexacyanoferrate as the anode and cathode materials, respectively. The reversible amination of redox-active phenazine moieties in dipyridophenazine and fast intercalation-deintercalation of protons in hexacyanoferrate enable the aqueous proton battery to achieve a reversible specific capacity of 37 mA h g-1 at 1 A g-1, good cycling stability with 76.1% capacity retention over 3000 cycles and excellent rate capability.

