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Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
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Step-growth or condensation polymerization is a stepwise reaction of bi or multifunctional monomers to form long-chain polymers. As all the monomers are reactive, most of the monomers are consumed at the early stages of the reaction to form small chains of reactive oligomers, which then combine to form long polymer chains in the late stages. Hence, the reaction has to proceed for a long time to achieve high molecular weight polymers.
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Microcracking in concrete refers to the tiny cracks that can form within the material even before any external load is applied. These microcracks typically occur at the interface between the coarse aggregate and the hydrated cement paste, often as a result of differential volume changes prompted by variations in stress-strain behavior, as well as thermal and moisture movement. Initially, these microcracks remain stable and do not grow substantially until the concrete is stressed to about 30...
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Lattice Centering and Coordination Number02:33

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The structure of a crystalline solid, whether a metal or not, is best described by considering its simplest repeating unit, which is referred to as its unit cell. The unit cell consists of lattice points that represent the locations of atoms or ions. The entire structure then consists of this unit cell repeating in three dimensions. The three different types of unit cells present in the cubic lattice are illustrated in Figure 1.
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Ziegler–Natta polymerization is another form of addition or chain‐growth polymerization used for synthesizing linear polymers over branched polymers. The catalyst used for polymerization is the Ziegler–Natta catalyst, named after Karl Ziegler and Giulio Natta, who developed it in 1953. This catalyst is an organometallic complex of titanium tetrachloride and triethyl aluminum, with the active form of the catalyst being an alkyl titanium compound. Using the Ziegler–Natta...
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The cationic polymerization mechanism consists of three steps: initiation, propagation, and termination. In the initiation step of the polymerization process, the π bond of a monomer gets protonated by the Lewis acid catalyst, which is formed from boron trifluoride and water. The protonation of the π bond generates a carbocation stabilized by the electron‐donating group. In the propagation step, the π bond of the second monomer acts as a nucleophile and attacks the...
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Mixed Mode Crack Propagation in Polymers Using a Discrete Lattice Method.

Matías Braun1, Josué Aranda-Ruiz2, José Fernández-Sáez2

  • 1Laboratory of Experimental Mechanics (LABMEX), INTEMA (Research Institute for Material Science and Technology), CONICET, Avda. Colón 10850, 7600 Mar del Plata, Argentina.

Polymers
|April 30, 2021
PubMed
Summary

This study introduces a novel discrete lattice model for simulating polymer fracture, overcoming limitations of previous models. The model accurately predicts crack patterns and mechanical behavior in polymethylmethacrylate under bending tests.

Keywords:
PMMAcrack propagationdiscrete methodexperimental testinglattice modelnumerical simulationthree-point bend

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Area of Science:

  • Materials Science
  • Computational Mechanics
  • Polymer Physics

Background:

  • Polymer fracture behavior is crucial for material design.
  • Existing discrete models often limit Poisson's coefficient selection.
  • Continuum and discrete methods are used for crack propagation analysis.

Purpose of the Study:

  • To present a numerical and experimental analysis of crack propagation in polymethylmethacrylate (PMMA) beams.
  • To introduce a discrete lattice model capable of simulating quasi-static fracture problems.
  • To overcome limitations in Poisson's coefficient selection in discrete fracture models.

Main Methods:

  • Developed a discrete numerical model using a regular triangular lattice with axial and normal interaction springs.
  • Incorporated a fracture criterion with a bilinear softening law, including fracture energy and progressive damage.
  • Conducted quasi-static three-point bending tests on PMMA beams with central and eccentric notches.
  • Validated the numerical model against experimental results.

Main Results:

  • The proposed lattice model accurately simulates quasi-static fracture problems.
  • Numerical results closely match experimental data for crack patterns.
  • The model effectively predicts peak load and initial stiffening behavior.
  • The model successfully addresses limitations in Poisson's coefficient selection.

Conclusions:

  • The discrete lattice model demonstrates significant capacity for simulating polymer fracture.
  • The model provides a viable alternative to continuum methods for crack propagation studies.
  • The approach allows for accurate prediction of fracture mechanics in polymers like PMMA.