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Updated: Nov 7, 2025

Selective Area Modification of Silicon Surface Wettability by Pulsed UV Laser Irradiation in Liquid Environment
Published on: November 9, 2015
An Experimental Investigation of Controlled Changes in Wettability of Laser-Treated Surfaces after Various Post
Tomáš Primus1, Pavel Zeman1, Jan Brajer1
1Department of Production Machines and Equipment, Faculty of Mechanical Engineering, Czech Technical University in Prague, 166 07 Prague, Czech Republic.
Abstract:
In this paper, a quick nanosecond laser micro structuring process was employed to change the surface wettability of Ti6Al4V alloy. The same laser structuring method was used throughout, but with varying input fluence. The laser processing parameters resulted in high surface melting. After laser treatment, four post-processing methods were used, namely high vacuum, low temperature annealing, storage in a polyethylene bag, and storage in ambient air. Subsequently, the water droplet contact angle was measured over a long time period of 55 days. The results show that the sample stored in ambient air remained hydrophilic. On the other hand, the sample post-processed in a vacuum chamber behaved hydrophobically with a contact angle of approximately 150°. Other post-processing did not lead to specific wettability behavior. After wettability testing, all samples were cleaned ultrasonically in distilled water. This cleaning process led to annulation of all obtained properties through post-processing. In summary, this paper shows that it is more important to study surface chemistry than topography in terms of effects on wettability. Moreover, surface wettability can be controlled by laser structuring, post-processing, and surface cleaning.
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