Degradation of 2,4-DCP using persulfate and iron/E-carbon micro-electrolysis coupling system

The greenhouse gas carbon dioxide (CO₂) was converted to a novel CO₂ conversion material (electrolytic carbon, EC) by molten salt electrochemical conversion, which served as the carbon source to prepare an iron-carbon composite (Fe-EC). The composite was used to activate persulfate (PS) and degrade 2,4-dichlorophenol (2,4-DCP) in an aqueous solution. The effects of several essential operating parameters such as PS dosage and pH on 2,4-DCP degradation were investigated. The removal efficiency of 2,4-DCP (20 mg L^-1) was 97.8% in the presence of Fe-EC (50 mg L^-1) and PS (1 mmol L^-1). Moreover, the average % reaction stoichiometric efficiency (RSE) (calculated for all selected times 5-60 min) was maintained at 23.07%. Electron paramagnetic resonance (EPR), classical radical scavenging experiments, and density functional theory (DFT) calculations were integrated for a mechanistic study, which disclosed that the active species in the system were identified as SO₄^⦁-, •OH, and O₂^⦁-. Moreover, the iron-carbon micro-electrolysis/PS (ICE-PS) system had a high tolerance to a wide range of pH, which would provide theoretical guidance for the treatment of organic pollutants in practical industrial wastewater.