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Updated: Nov 6, 2025
![[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
A copper complex of an unusual hy-droxy-carboxyl-ate ligand: [Cu(bpy)(C4H4O6)]
Sen Gao1, Frank R Fronczek1, Andrew W Maverick1
1Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803, USA.
Abstract:
A copper(II) complex, (2,2'-bi-pyridine-κ2 N,N')[2-hy-droxy-2-(hy-droxy-methyl-κO)propane-dioato-κ2 O 1,O 3]copper(II), [Cu(C4H4O6)(C10H8N2)], containing the unusual anionic chelating ligand 2-(hy-droxy-meth-yl)tartronate, has been synthesized. [Cu(bpy)2(NO3)](NO3) was mixed with ascorbic acid and Dabco (1,4-di-aza-bicyclo-[2.2.2]octa-ne) in DMF (dimethylformamide) solution in the presence of air to produce the title compound. The structure consists of square-pyramidal complexes that are joined by Cu⋯O contacts [2.703 (2) Å] into centrosymmetric dimers. The C4H4O6 2- ligand, which occupies three coordination sites at Cu, has previously been identified as an oxidation product of ascorbate ion.
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