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Published on: September 13, 2024
Easy wide scope access to luminescent fluorophosphoranes
Jaime Ponce-de-León1, Rebeca Infante1, Pablo Espinet1
1IU CINQUIMA/Química Inorgánica, Facultad de Ciencias, Universidad de Valladolid, Valladolid-47071, Spain. espinet@qi.uva.es.
Abstract:
The almost quantitative synthesis of homologous luminescent fluorophosphoranes, by SNAr cyclization of (2'-F,2-(PR2)biaryl) phosphines made from easily accessible reagents, is reported and the DFT cyclization mechanism and alternative pathways to complete this isomerization are studied and discussed.
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