Phototunable Cloud Point Temperatures Stemming from Cyclic Topology: Synthesis and Thermal Phase Transition Behavior...

Cyclic polymers possess distinct properties compared with their linear counterparts, such as smaller hydrodynamic volume, lower viscosity, and higher glass-transition temperature, etc. To explore the impact of the cyclic topology on the thermo-induced phase transition behavior of poly(N-acryloylsarcosine methyl ester) (PNASME), the anthracene-terminated telechelic PNASMEs are synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization of monomer NASME using a bifunctional chain transfer agent (CTA) with two anthryl groups. Subsequently, cyclic PNASMEs are prepared via UV-induced cyclization under 365 nm UV. There are considerable increases (up to 50 °C) for the cloud point temperatures (T_cp s) of cyclic PNASMEs compared with the linear counterparts. In view of the increment, the T_cp of PNASME is tuned by varying the cyclic/linear ratio (the molar ratio between cyclic PNASME and linear PNASME in the product) with different irradiation time.