A rational design of g-C₃N₄-based ternary composite for highly efficient H₂ generation and 2,4-DCP degradation

In this work, g-C₃N₄ based ternary composite (CeO₂/CN/NH₂-MIL-101(Fe)) has been fabricated via hydrothermal and wet-chemical methods. The composite showed superior photoactivities for H₂O reduction to produce H₂ and 2,4-dichlorophenol (2,4-DCP) degradation. The amount of H₂ evolved over the composite under visible and UV-visible irradiations is 147.4 µmol·g^-1·h^-1 and 556.2 µmol·g^-1·h^-1, respectively. Further, the photocatalyst degraded 87% of 2,4-DCP in 2 hrs under visible light irradiations. The improved photoactivities are accredited to the synergistic-effects caused by the proper band alignment with close interfacial contact of the three components that significantly promoted charge transfer and separation. The 2,4-DCP degradation over the composite is dominated by OH radical rather than h⁺ and O₂^- as investigated by scavenger trapping experiments. This is further supported by the electron para-magnetic resonance (EPR) study. This work provides new directions for the development of g-C₃N₄ based highly efficient ternary composite materials for clean energy generation and pollution control.