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Updated: Nov 6, 2025

Influence of Hybrid Perovskite Fabrication Methods on Film Formation, Electronic Structure, and Solar Cell Performance
Published on: February 27, 2017
Rapid hybrid perovskite film crystallization from solution
Sandy Sánchez1, Lukas Pfeifer2, Nikolaos Vlachopoulos3
1Laboratory of Photomolecular Sciences, Institute of Chemistry and Chemical Engineering, École Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland. sandy.sanchezalonso@epfl.ch anders.hagfeldt@epfl.ch and Laboratory of Photonics and Interfaces, Institute of Chemistry and Chemical Engineering, École Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland.
This review explores perovskite thin film formation using solution processing and rapid thermal annealing. Precise control over crystal growth via photonic sintering enhances material quality and device performance.
Area of Science:
- Materials Science
- Chemical Engineering
- Solid State Physics
Background:
- Solution processing enhances perovskite thin film material processability.
- Tuning physicochemical properties requires control over solution precursors and crystal growth.
- Understanding kinetic phenomena is crucial for thin-film formation.
Purpose of the Study:
- To review the state-of-the-art in perovskite hybrid crystal growth.
- To provide a comprehensive theoretical description and experimental investigation overview.
- To highlight the role of rapid thermal annealing and photonic sintering.
Main Methods:
- Review of theoretical models for perovskite crystallization.
- Analysis of experimental investigations on thin-film formation.
- Focus on rapid thermal annealing and photonic sintering techniques.
Main Results:
- Controlling crystal growth with high-precision photonic sintering simplifies experimental analysis.
- New empirical parameter spaces are opened by advanced synthesis methods.
- Enhanced understanding of perovskite crystallization kinetics.
Conclusions:
- Improved perovskite synthesis and thin-film quality are achievable.
- Precise control over nucleation and crystal growth is key.
- Higher device performances are expected with optimized synthesis.
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