Synthesis of New Quinoline-Conjugated Calixarene as a Fluorescent Sensor for Selective Determination of Cu²⁺ Ion

A novel quinoline-functionalized calix [4] arene derivative (Quin-Calix) has been successfully synthesized at partial cone conformation and duly characterized by using FTIR, ¹H-NMR, ¹³C-NMR, ESI-MS and elemental analysis techniques. Moreover, the cation-binding property of the calix [4] arene derivative (Quin-Calix) has been investigated towards Cu²⁺, Ba²⁺, Cd²⁺, Co²⁺, Ni²⁺, Zn²⁺ and Fe³⁺ ions, and the recognition event monitored by UV-Vis absorption and fluorescence studies. The results indicated that Quin-Calix displays a remarkable affinity and selectivity only for Cu²⁺ ion. The binding constant and stoichiometry of the complex formed between Quin-Calix and Cu²⁺ ion have been also calculated from the fluorescence data. In addition, Stern-Vohmer equation has been used to elucidate the mechanism of quenching.