Catalytic degradation of caffeic acid by DBD plasma and Mn doped cobalt oxyhydroxide catalyst

In this study, caffeic acid (CA) was degraded by electrical discharge plasma combined with Mn doped CoOOH catalyst. Doping of Mn significantly improve the catalytic activity of CoOOH. CA degradation efficiency was 75.6% with dielectric barrier discharge treatment for 10 min, and it reached 97% using CoOOH as the catalyst at the same treatment time. CA was 100% degraded with only 8 min using Mn/CoOOH as the catalyst. The introduction of Mn into the lattice of CoOOH induced the formation of oxygen vacancy, causing part of coordinate number of Co decreased from 6 to 5, and thus produces unsaturated Co to be the Lewis acid sites. Lewis acid sites (unsaturated Co) could coordinate with O₃ and H₂O₂ and break their chemical bonds to form O and -OH. Assisting in the conversion of O₃ to ·OH was the main role of H₂O₂ in the catalytic process. The degradation products and pathway of CA were studied by three-dimensional fluorescence, liquid chromatograph-mass spectrometer and density functional theory calculations.