Influence of drying and calcination temperatures for Ce-Cu-Al trimetallic composite catalyst on simultaneous removal...

This work explored the influences of the drying and calcination temperatures on a Ce-Cu-Al trimetallic composite catalyst for the simultaneous removal of H₂S and PH₃. The effects of both temperatures on the structural features and activity were examined. The density functional theory method was used to calculate adsorption energies and further analyze their adsorption behavior on different slabs. Experiments revealed suitable drying and calcination temperatures to be 60 and 500°C, respectively. The capacity reached 323.8 and 288.1 mg/g. Adjusting drying temperature to 60°C is more inclined to form larger and structured grains of CuO. Rising calcinating temperature to 500°C could increase the grain size and redox capacity of CuO to promote performance. Higher temperatures would destroy the surface structure and lead to a crystal phase transformation, which was that the CuO and Al₂O₃ were gradually recombined into CuAl₂O₄ with a spinel structure. The exposed crystal planes of surficial CuO and CuAl₂O₄ were determined according to characterization results. Calculation results showed that, compared with CuO (111), H₂S and PH₃ have weaker adsorption strength on CuAl₂O₄ (100) which is not conducive to their adsorption and removal.