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Synthesis of Esters Via a Greener Steglich Esterification in Acetonitrile
Published on: October 30, 2018
Linear group 13 E[triple bond, length as m-dash]E triple bonds
Zhong-Hua Cui1, Yu-Qian Liu2, Runfeng Huang3
1Institute of Atomic and Molecular Physics, Key Laboratory of Physics and Technology for Advanced Batteries (Ministry of Education), Jilin University, Changchun, China. zcui@jlu.edu.cn and Beijing National Laboratory for Molecular Sciences, China.
Abstract:
The unexpected linear group 13 E[triple bond, length as m-dash]E triple bonds were herein uncovered with the D3h-symmetry E2M5+ (M = Li, Na, and K) clusters, where the linear M-E[triple bond, length as m-dash]E-M form is perfectly surrounded by M3 motifs. The increasing nonbonded electron density of the heavier main-group elements is the key issue for the trans-bent geometry, and yet it is strongly suppressed in E2M5+, creating two degenerate π bonds and one multi-center σ bond.
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