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Updated: Nov 5, 2025
Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Synthesis, structures and stability of three V-substituted polyoxoniobate clusters based on [TeNb9O33]17- units
Zongfei Yang1, Jingjing Shang1, Yuanyuan Yang1
1Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, China. jyniu@henu.edu.cn jpwang@henu.edu.cn.
Abstract:
Three structurally intriguing polyoxoniobates (PONbs) based on the trivacant B-type α-Keggin ion {TeNb9O33}, H4K(CN3H6)2{[Cu4(2,2'-bipy)4(H2O)2][TeNb9V2O37]}·29H2O (1, 2,2'-bipy = 2,2'-bipyridine), H0.5K5Na2.5{[Cu(en)H2O]3[TeNb9V3O39]}·10H2O (2, en = ethylenediamine), and K3Na5{[Cu(1,3-dap)H2O]3[TeNb9V3O39]}·11H2O (3, 1,3-dap = 1,3-diaminopropane), are assembled by the conventional aqueous solution methods using a series of N-containing organic ligands. In 1, each of the two {VO4} units is attached to two coplanar NbO6 octahedra on the {Nb3O13} cluster of the {TeNb9O33} unit. Differently, three {VO4} units in 2 and 3 are linked to two edge-sharing NbO6 octahedra, respectively. Compounds 1-3 represent the first oxo NbTeV clusters and also the first vanadoniobates based on the trivacant Keggin PONb units. All three compounds were characterised by single-crystal X-ray structural analysis, TGA and IR, ESI-MS and 51V NMR spectroscopy. Furthermore, the magnetic properties of compounds 1 and 2 were also studied.
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