Preparation and luminescence properties of ZnWO₄ :Eu³⁺ ,Tb³⁺ phosphors

A series of ZnWO₄ :Eu³⁺ ,Tb³⁺ phosphors was prepared using a co-precipitation method at room temperature. The structures and luminescence properties of the materials were characterized using X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, and UV-vis light, differential thermal analysis-thermogravimetric analysis, fluorescence spectra and the calculated Commission Internationale de l'Éclairage (CIE) coordinates. The results showed that the material had a monoclinic structure and the P2/c group was determined using XRD. FTIR spectroscopy confirmed the existence of W-O, Zn-O bonds, and Zn-O-W groups in WO₆ and ZnO₆ octahedra. In the excitation spectrum, there was an overlap of the broad band charge transfer bands belonging to O^2- →W⁶⁺ and O^2- →Eu³⁺ or O^2- →Tb³⁺ transitions in the range 200-325 nm, and excitation bands between 350 and 500 nm belonged to the characteristic absorption bands for Eu³⁺ and Tb³⁺ . Therefore, the phosphor can be used as a single component tunable phosphor in light-emitting diodes.