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Published on: January 26, 2016
Simultaneous memory effects in the stress and in the dielectric susceptibility of a stretched polymer glass
J Hem1, C Crauste-Thibierge1, F Clément2
1Univ of Lyon, Ens de Lyon, Univ Claude Bernard, CNRS, Laboratoire de Physique, UMR 5672, F-69342 Lyon, France.
Abstract:
We report experimental evidence that a polymer stretched at constant strain rate λ[over ̇] presents complex memory effects after λ[over ̇] is set to zero at a specific strain λ_{w} for a duration t_{w}, ranging from 100s to 2.2×10^{5}s. When the strain rate is resumed, both the stress and the dielectric constant relax to the unperturbed state nonmonotonically. The relaxations depend on the observable, on λ_{w} and on t_{w}. Relaxation master curves are obtained by scaling the time and the amplitudes by ln(t_{w}). The dielectric evolution also captures the distribution of the relaxation times, so the results impose strong constraints on the relaxation models of polymers under stress and they can be useful for a better understanding of memory effects in other disorder materials.
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