Understanding Oxygen Release from Nanoporous Perovskite Oxides and Its Effect on the Catalytic Oxidation of CH₄ and...

The design of nanoporous perovskite oxides is considered an efficient strategy to develop performing, sustainable catalysts for the conversion of methane. The dependency of nanoporosity on the oxygen defect chemistry and the catalytic activity of perovskite oxides toward CH₄ and CO oxidation was studied here. A novel colloidal synthesis route for nanoporous, high-temperature stable SrTi_0.65Fe_0.35O_3-δ with specific surface areas (SSA) ranging from 45 to 80 m²/g and pore sizes from 10 to 100 nm was developed. High-temperature investigations by in situ synchrotron X-ray diffraction (XRD) and TG-MS combined with H₂-TPR and Mössbauer spectroscopy showed that the porosity improved the release of surface oxygen and the oxygen diffusion, whereas the release of lattice oxygen depended more on the state of the iron species and strain effects in the materials. Regarding catalysis, light-off tests showed that low-temperature CO oxidation significantly benefitted from the enhancement of the SSA, whereas high-temperature CH₄ oxidation is influenced more by the dioxygen release. During isothermal long-term catalysis tests, however, the continuous oxygen release from large SSA materials promoted both CO and CH₄ conversion. Hence, if SSA maximization turned out to efficiently improve low-temperature and long-term catalysis applications, the role of both reducible metal center concentration and crystal structure cannot be completely ignored, as they also contribute to the perovskite oxygen release properties.