Oxygen Vacancies Boosting Lithium-Ion Diffusion Kinetics of Lithium Germanate for High-Performance Lithium Storage

Oxygen vacancies play a positive role in optimizing the physical and chemical properties of metal oxides. In this work, we demonstrated oxygen vacancy-promoted enhancement of Li-ion diffusion kinetics in Li₂GeO₃ nanoparticle-encapsulated carbon nanofibers (denoted as Li₂GeO_3-/C) and accordingly boosted lithium storage. The introduction of the oxygen vacancies in Li₂GeO_3-/C can enhance electronic conductivity and evidently decrease activation energy of Li-ion transport, thus resulting in evidently accelerated Li-ion diffusion kinetics during the lithiation/delithiation process. Thus, the Li₂GeO_3-/C nanofibers exhibit an exceptionally large discharge capacity of 1460.5 mA h g^-1 at 0.1 A g^-1, high initial Coulombic efficiency of 81.3%, and excellent rate capability. This facile and efficient strategy could provide a reference for injecting the oxygen vacancies into other metal oxides for high-performance anode materials.