Site-Selective Transformation for Preparing Tripod-like NiCo-Sulfides@Carbon Boosts Enhanced Areal Capacity and...

Flexible power supply systems for future wearable electronics desperately require high areal capacity (C_a) and robust cycling reliability due to the limited surface area of the human body. Transition metal sulfides are preferred as cathode materials for their improved conductivity and rich redox centers, yet their practical applications are severely hindered by the sluggish charge transport kinetics and unavoidable capacity decay due to the phase transformation during charge/discharge processes. Herein, we develop a site-selective transformation strategy for preparing tripod-like NiCo-sulfides@carbon (T-NCS@C) arrays on carbon cloth. The mass loading of active materials is balanced with charge (electron and ion) transport efficiency. The optimized T-NCS@C delivers a superior C_a of 494 μA h/cm² (corresponding to 235 mA h/g) at 3 mA/cm². Due to the protection of the carbon layer that is derived from transformed metal-organic framework (MOF) sheath, the T-NCS@C displays excellent stability with 92% retention over 5000 charge/discharge cycles. The flexible full cell adopting Fe₂O₃ as the anode and T-NCS@C as the cathode exhibits an improved E_a (areal energy density) of 389 μW h/cm² at a P_a (areal power density) of 4.22 mW/cm² together with robust cycling reliability.