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Related Concept Videos

P-N junction01:11

P-N junction

A p-n junction is formed when p-type and n-type semiconductor materials are joined together. At the interface of the p-n junction, holes from the p-side and electrons from the n-side begin to diffuse into the opposite sides due to the concentration gradient. This diffusion of carriers leads to a region around the junction where there are no free charge carriers, known as the depletion region. The charge density within the depletion region for the n-side and p-side can be described by the...

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Updated: Jun 24, 2026

Influence of Hybrid Perovskite Fabrication Methods on Film Formation, Electronic Structure, and Solar Cell Performance
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Toward Large-Area and Fully Solution-Sheared Perovskite Solar Cells.

Gizachew Belay Adugna1,2,3, Seid Yimer Abate1, Wen-Ti Wu1

  • 1Institute of Chemistry, Academia Sinica, Nankang, Taipei 115, Taiwan.

ACS Applied Materials & Interfaces
|May 25, 2021
PubMed
Summary

Solution shearing fabricates large-area perovskite solar cells (PSCs). Fully solution-sheared PSCs achieved 15.89% efficiency, while hybrid methods reached 17.27%, showing potential for scalable PSC production.

Keywords:
fully sheared perovskite solar cellslarge-area perovskite filmperovskite film morphologyperovskite solar cellsolution shearing

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Area of Science:

  • Materials Science
  • Renewable Energy

Background:

  • Perovskite solar cells (PSCs) offer promising photovoltaic performance.
  • Scalable fabrication methods are crucial for commercializing PSCs.
  • Solution-based techniques are attractive for large-area device manufacturing.

Purpose of the Study:

  • To investigate the efficacy of solution shearing for fabricating large-area PSCs.
  • To optimize film morphology and thickness using the solution shearing technique.
  • To compare the performance of fully solution-sheared PSCs with hybrid fabrication approaches.

Main Methods:

  • Utilized the solution shearing technique to deposit layers for PSCs with a device structure of FTO/c-TiO2/mp-TiO2/CH3NH3PbI3/Spiro-OMeTAD/Ag.
  • Optimized film morphology and thickness by adjusting shearing parameters for each layer.
  • Fabricated large-area devices up to 6 × 10 cm².

Main Results:

  • Fully solution-sheared PSCs achieved a champion power conversion efficiency (PCE) of 15.89%.
  • PSCs with a solution-sheared perovskite layer and spin-coated other layers reached a PCE of 17.27%.
  • Demonstrated control over film properties through solution shearing parameter optimization.

Conclusions:

  • Solution shearing is a viable, rapid, and cost-effective method for large-area PSC fabrication.
  • The technique shows potential for producing scalable PSC modules.
  • Hybrid approaches combining solution shearing with other methods can yield high-efficiency devices.