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Updated: Nov 4, 2025
Facet-to-facet Linking of Shape-anisotropic Colloidal Cadmium Chalcogenide Nanostructures
Published on: August 10, 2017
Retention of a Four-Fold Interpenetrating Cadmium-Organic Framework through a Three-Step Single Crystal
Jia-Qian Li1, Si-Wen Ke1, Tong Yan1
1State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, China.
Abstract:
Controlled hydration leads to four derivatives of a metal-organic framework consisting of cadmium ions, N1,N1,N4,N4-tetrakis(4-(pyridin-4-yl)phenyl)benzene-1,4-diamine, and coordinated and free nitrates. The balance of water coordination and the multitude of bonding of the weakly coordinated nitrate lead to a progressive change in the coordination number of the Cd2+ ions from eight to seven to six without great perturbation to the 4-fold interpenetration three-dimensional framework.
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