Thermal Activation of Nanoscale Wear

Nanoscale wear tracks on ionic crystals are created by reciprocating single asperity scratch tests using atomic force microscopy. The wear characteristics are analyzed by the scratch depth as a function of surface temperature from 25 to 300 K. The average wear depth shows a nonmonotonic behavior as a function of temperature, with a transition between two different regimes characterized by the occurrence of quasiperiodic ripple formation. A thermally activated bond breaking model quantitatively explains the wear data in the low temperature, nonripple regime, but fails above the temperature threshold. This discrepancy is resolved with a geometric separation of the ripple mounds from the troughs, leading to full agreement with Arrhenius kinetics over the full temperature range.