A review on TiO₂-based photocatalytic systems applied in fruit postharvest: Set-ups and perspectives

Titanium dioxide (TiO₂) is a photocatalytic material used to degrade ethylene, and it has been studied as an alternative postharvest technology. Although several studies have indicated the effective action of TiO₂ photocatalysis for delaying the fruit ripening, photocatalytic systems need to be well-designed for this application. Fruit is susceptible to environmental conditions like temperature, relative humidity, atmosphere composition and exposure to UV-light. This fragility associated with its variable ethylene production rate over its maturation stage limits the photocatalysis parameters optimization. Thus, this review aims to detail the reaction mechanisms, set-up, advantages, and limitations of TiO₂ photocatalytic systems based on polymers-TiO₂ nanocomposites and reactors containing TiO₂ immobilized into inorganic supports designed for fruit applications. It is expected that this review can elucidate the fundamental aspects that should be considered for the use of these systems.