Anion Exchange Composite Membranes Composed of Quaternary Ammonium-Functionalized Poly(2,6-dimethyl-1,4-phenylene...

Anion exchange membranes (AEMs) with good alkaline stability and ion conductivity are fabricated by incorporating quaternary ammonium-modified silica into quaternary ammonium-functionalized poly(2,6-dimethyl-1,4-phenylene oxide) (QPPO). Quaternary ammonium with a long alkyl chain is chemically grafted to the silica in situ during synthesis. Glycidyltrimethylammoniumchloride functionalization on silica (QSiO₂) is characterized by Fourier transform infrared and transmission electron microscopic techniques. The QPPO/QSiO₂ membrane having an ion exchange capacity of 3.21 meq·g^-1 exhibits the maximum hydration number (λ = 11.15) and highest hydroxide ion conductivity of 45.08 × 10^-2 S cm^-1 at 80 °C. In addition to the high ion conductivity, AEMs also exhibit good alkaline stability, and the conductivity retention of the QPPO/QSiO₂-3 membrane after 1200 h of exposure in 1 M potassium hydroxide at room temperature is about 91% ascribed to the steric hindrance offered by the grafted long glycidyl trimethylammonium chain in QSiO₂. The application of the QPPO/QSiO₂-3 membrane to an alkaline fuel cell can yield a peak power density of 142 mW cm^-2 at a current density of 323 mA cm^-2 and 0.44 V, which is higher than those of commercially available FAA-3-50 Fumatech AEM (OCV: 0.91 V; maximum power density: 114 mW cm^-2 at current density: 266 mA cm^-2 and 0.43 V). These membranes provide valuable insights on future directions for advanced AEM development for fuel cells.