Anaerobic Corrosion of Zero-Valent Iron at Elevated Temperatures

Increasing groundwater temperatures caused by global warming, subsurface infrastructure, or heat storage projects may interfere with groundwater remediation techniques using zero-valent iron (ZVI) technology by accelerating anaerobic corrosion. The corrosion behavior of three ZVIs widely used in permeable reactive barriers (PRBs), Peerless cast iron (PL), Gotthart-Maier cast iron (GM), and an ISPAT iron sponge (IS), was investigated at temperatures between 25 and 70 °C in half-open batch reactors by measuring the volume of hydrogen gas generated. Initially, the corrosion rates of all tested ZVIs increased with temperature; at temperatures ≤40 °C, a material-specific steady state is reached, and at temperatures >40 °C, passivation causes a decrease in long-term corrosion rates. The observed corrosion behavior was therefore assumed to be superimposed by accelerating and inhibiting effects, caused by surface precipitates where the fitting of measured corrosion rates by a modeling approach, using the corroded amount of Fe⁰ to account for passivating minerals, yields intrinsic activation energies (E_a, _ZVI) of 81, 90, and 107 kJ mol^-1 for IS, GM, and PL, respectively. An increase in H₂ production might not be directly transferable to an increase in general ZVI reactivity; however, the results suggest that an increase in chlorinated hydrocarbon degradation rates can be expected for ZVI-PRBs in the immediate vicinity of low-temperature underground thermal energy storages (UTESs) or in the impact areas of high-temperature UTES with temperatures of ≤40 °C.