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Updated: Nov 3, 2025

Fabrication and Testing of Catalytic Aerogels Prepared Via Rapid Supercritical Extraction
Published on: August 31, 2018
Reduction of PVA Aerogel Flammability by Incorporation of an Alkaline Catalyst
Zhi-Han Cheng1, Mo-Lin Guo1, Xiao-Yi Chen1
1Department of Macromolecular Science & Engineering, Case Western Reserve University, Cleveland, OH 44106, USA.
Abstract:
Sodium hydroxide was used as a base catalyst to reduce the flammability of poly(vinyl alcohol) (PVA) aerogels. The base-modified aerogels exhibited significantly enhanced compressive moduli, likely resulting in decreased gallery spacing and increased numbers of "struts" in their structures. The onset of decomposition temperature decreased for the PVA aerogels in the presence of the base, which appears to hinder the polymer pyrolysis process, leading instead to the facile formation of dense char. Cone calorimetry testing showed a dramatic decrease in heat release when the base was added. The results indicate that an unexpected base-catalyzed dehydration occurs at fire temperatures, which is the opposite of the chemistry normally observed under typical synthesis conditions.
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