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Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
Published on: November 21, 2017
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Applications of Hybrid Polymers Generated from Living Anionic Ring Opening Polymerization
Jonathan Goff1, Santy Sulaiman1, Barry Arkles1
1Gelest Inc., 11 Steel Road East, Morrisville, PA 19067, USA.
Molecules (Basel, Switzerland)
|June 2, 2021
Summary
Living Anionic Ring-Opening Polymerization (AROP) enables precise control over siloxane macromers for advanced materials. These polymers offer unique silicone properties, driving diverse commercial applications from medical devices to electronics.
Area of Science:
- Polymer Chemistry
- Materials Science
Background:
- Living Anionic Ring-Opening Polymerization (AROP) provides precise control over polymer architecture.
- Siloxane macromers incorporate silicone properties into organic structures, offering unique characteristics like low glass transition temperature, hydrophobicity, and low surface energy.
Purpose of the Study:
- To review the historical development and commercial applications of polymers derived from Living AROP, with a focus on siloxane macromers.
- To highlight applications where these polymers are produced and sold on a commercial scale.
- To discuss emerging hybrid polymers with potential in advanced fields.
Main Methods:
- Review of historical technological development.
- Emphasis on commercially scaled applications.
- Discussion of hybrid polymers and their potential uses.
Main Results:
- Living AROP has enabled the development of advanced materials with tailored properties.
- Siloxane macromers are increasingly utilized in diverse commercial products, including medical devices, microelectronics, and packaging.
- Hybrid polymers show promise for applications in photoresist, biomimetic materials, and liquid crystals.
Conclusions:
- Precise control over polymer architectures via Living AROP is crucial for advanced material applications.
- The unique properties of silicones, when incorporated into organic structures, enable high-performance materials for various industries.
- Continued research into hybrid polymers derived from Living AROP is expected to yield novel applications.
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