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Published on: February 25, 2017
Nano-Crystal and Microstructure Formation in Fluoride Photo-Thermo-Refractive Glass Using Chirp-Controlled Ultrafast
Yunjie Zhang1, Xu Wang2, Guodong Zhang3
1School of Science, Xi'an Polytechnic University, Xi'an 710048, China.
Abstract:
Nano-crystals were formed in the exposed regions of photo-thermo-refractive glass undergoing irradiation with zeroth order chirp-controlled ultrafast laser Bessel beams and subsequent heat treatment. Effects of various writing powers, pulse durations and heat treatment time on the distribution and the size of the nano-crystals were investigated. The results show that nano-crystals' distribution depended on the laser power density spatial shape, while the size of the nano-crystals is quasi-independent. However, the average diameter of the nano-crystals was affected by the heat treatment time, decreasing from 175 to 105 nm with the time halved. In addition, using crystallographic characterization by X-ray diffraction, the nano-crystal composition in the laser-exposed regions was detected to be sodium fluoride.

