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Portable Raman Spectrometer as a Screening Tool for Characterization of Iberian Dry-Cured Ham
Andrés Martín-Gómez1, Natalia Arroyo-Manzanares2, María García-Nicolás2
1Department of Analytical Chemistry, Institute of Fine Chemistry and Nanochemistry, Marie Curie Annex Building, Campus de Rabanales, 14071 Córdoba, Spain.
Abstract:
Dry-cured Iberian ham is officially classified into different commercial categories according to the pig's breed and feeding regime. These reach very different prices, thus promoting labelling fraud and causing great damage to the food sector. In this work, a method based on Raman spectroscopy was explored as a rapid in situ screening tool for Iberian ham samples. A total of 110 samples were analyzed to assess the potential of this technique to differentiate purebred, crossbred, acorn-fed and feed-fed dry-cured Iberian ham. A continuous signal probably due to sample fluorescence was obtained, which hid the Raman scattering signal. Therefore, chemometric treatment was applied in order to extract non-apparent information. High validated classification rates were obtained for feeding regime (83.3%) and breed (86.7%). In addition, an interlaboratory study was carried out to confirm the applicability of the method with 52 samples, obtaining a validated rate above 80%.
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