Biosorption of Cu²⁺, Pb²⁺, Cd²⁺ and their mixture from aqueous solutions by Michelia figo sawdust

The study aimed at investigating copper, lead, and cadmium removal from both single and mixed metal solutions by Michelia figo (Lour.) Spreng. wood sawdust treated with 0.5 mol l^-1 NaOH for four hours. In order to evaluate the effects of each factor and interactions between factors on metal ion biosorption, a 2³ factorial experimental design was applied. FTIR results showed that the metal ions would bind to the hydroxyl and carboxyl groups of M. figo wood sawdust biomass. The main effects and interactions of three factors pH (3 and 5), initial metal ion concentration (C₀, 0.157 and 1.574 mmol L^-1), and dosage of biomass (D, 4 and 10 g L^-1) at two levels were analyzed. The most significant variable regarding Cu²⁺ and Pb²⁺ biosorption was initial metal iron concentration. For Cd²⁺, pH was found to be the most significant factor. The maximum removal efficiencies were 94.12 and 100% for Cu²⁺ and Cd²⁺, respectively, at conditions of (+ 1, - 1, + 1): pH 5, initial metal concentration 0.157 mmol L^-1 and dosage of biomass 10 g L^-1, while 96.39% for Pb²⁺ at conditions of (- 1, - 1, + 1): pH 3, initial metal concentration 0.157 mmol L^-1 and dosage of biomass 10 g L^-1. There were some interactions between factors: pH*C₀ and C₀*D for Cu²⁺, pH*C₀, pH*D and C₀*D for Pb²⁺, pH*C₀ and C₀*D for Cd²⁺. Biosorption from a multi metal system showed that the presence of Cu²⁺ and Cd²⁺ had no significant influence on the Pb²⁺ removal, while Pb²⁺ in solution significantly decreased the removal efficiencies of the other two metals.