Vanadium selenide decorated reduced graphene oxide nanocomposite: A co-active catalyst for the detection of 2,4,6 -...

Transition metal chalcogenides (TMCs) have great potential in diverse electrochemical technologies owing to their unique characteristics. In the present work, we portray the design and synthesis of Vanadium selenide (V₂Se₉)/reduced graphene oxide (rGO) forming a two-dimensional (2D) hybrid nanocomposite via a simple hydrothermal method. The successfully synthesized nanocomposite underwent in-depth surface and morphological characterizations by XRD, Raman spectroscopy, XPS, TEM, STEM and its potential as an electro catalyst was investigated by using glassy carbon electrode (GCE) for the detection of 2,4,6-trichlorophenol (TCP). The structural features favored a high charge transfer ratio, high surface area as well as excellent conductivity and catalytic activity. The V₂Se₉/rGO/GCE modified electrode showed a low charge transfer resistance (R_ct) of 54.057 Ω cm², a decent detection limit (LOD) of 35.07 nM and a very high sensitivity of 22 μA μM^-1 cm^-2 in a working range of 0.001 μM-1150 μM. This is due to the active proton interaction, surface enhancement, and positive synergistic effect between rGO and V₂Se₉. The proposed sensor has good detection potential in agricultural soil, river water, fish, and beverage samples like wine and apple juice. The obtained results from our investigation would elucidate the application of the catalyst in electrochemical sensors.