An electro-oxidation reactor for treatment of nanofiltration concentrate towards zero liquid discharge

Nanofiltration (NF) concentrate generated from the secondary wastewater treatment contains high concentration of ammonium nitrogen and refractory organics, thus having great environmental risks. In this study, an electro-oxidation (EO) reactor built up with a boron-doped diamond (BDD) anode is utilized to treat the NF concentrate. To reach "zero liquid discharge", a mixture of the electrolytic effluent and the raw secondary wastewater was collected and transported back to the NF module. Results show that under the current density of 30 mA·cm^-2, most of ammonia nitrogen was decomposed into N-gases within 30 min due to the active chlorine radicals generated in the electrochemical process. Moreover, the EO reactor completely eliminated antibiotics, humic acids and bacteria in the NF concentrate under long electrolysis time of 60 min. In particular, the organic pollutants removal rate was kept at a stable value in the EO reactor for a long-term operation of up to 120 h. In addition, the NF membrane remained a constant permeate flux without being affected by the membrane biofouling caused by organic components in wastewater. Our study highlights the potential of the NF-EO process as a "zero liquid discharge" approach for treatment of the secondary wastewater.