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Spin-Spin Interactions in One-Dimensional Assemblies of a Cumulene-Based Singlet Biradical
Yasukazu Hirao1, Yoko Daifuku1, Keiji Ihara1
1Department of Chemistry, Graduate School of Science, Osaka University, 1-1 Machikaneyama, Toyonaka, Osaka, 560-0043, Japan.
Abstract:
The synthesis of phenalenyl-endcapped [5]cumulene as a cumulene-based singlet biradical and the spin correlation changes of one-dimensional aggregates are described. The high propensity for self-aggregation of phenalenyl rings and the introduction of bulky substituents into the appropriate positions led to the formation of a one-dimensional chain assembly. Single-crystal X-ray structural analysis indicated that the bond length alternation of the cumulene chain increased with decreasing temperature, along with improved overlapping of the phenalenyl rings. Variable-temperature Raman spectroscopy and magnetic susceptibility measurements revealed that a localized spin pair within the molecule decouples at low temperatures, and a continuum spin system involving intra- and intermolecular spin-spin interactions emerges in the one-dimensional chain.
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