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Updated: Nov 2, 2025

Single-throughput Complementary High-resolution Analytical Techniques for Characterizing Complex Natural Organic Matter Mixtures
Published on: January 7, 2019
An ionic covalent organic framework for rapid extraction of polar organic acids from environmental waters
Jing Sun1, Fang Xue1, Cui-Ling Gao2
1Qilu University of Technology (Shandong Academy of Science), Shandong Analysis and Test Center, School of Environmental Science and Engineering, Jinan, 250014, P. R. China. j05hx121@126.com.
Abstract:
An ionic covalent organic framework (Fe3O4@EB-TFB-iCOF) as a polar adsorbent was synthesized and characterized. It was applied in the magnetic solid phase extraction (MSPE) of four polar organic acids, namely, 2-(2,4,5-trichlorophenoxy)propionic acid, 2-methyl-4-chlorophenoxy acetic acid, naphthyloxyacetic acid, and naphthylacetic acid. The organic acids were detected by high performance liquid chromatography-ultraviolet analysis (HPLC-UV). A method for the determination of organic acids based on MSPE-HPLC-UV was established. The method shows good linear regression (R2≥ 0.9950), high precision (1.53-3.80%, n = 6), and low detection limit (0.10-0.49 ng mL-1). The recovery rate of environmental water samples ranges from 73.3% to 101.0%. This method provides a possibility for high sensitivity analysis of polar organic acids.
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