Host-Guest Interaction in Ethylene and Ethane Separation on Zeolitic Imidazolate Frameworks as Revealed by
Yuqing Xiao1,2, Yueying Chu1, Shenhui Li1
1State Key Laboratory of Magnetic Resonance, and Atomic and Molecular Physics, National Center for Magnetic Resonance in Wuhan, Wuhan Institute of Physics and Mathematics, Innovation Academy for Precision Measurement, Science and Technology, Chinese Academy of Sciences, Wuhan, 430071, P. R. China.
Abstract:
The separation of ethane/ethylene mixture by using metal-organic frameworks (MOFs) as adsorbents is strongly associated with the pore size-sieving effect and the adsorbent-adsorbate interaction. Herein, solid-state NMR spectroscopy is utilized to explore the host-guest interaction and ethane/ethylene separation mechanism on zeolitic imidazolate frameworks (ZIFs). Preferential access to the ZIF-8 and ZIF-8-90 frameworks by ethane compared to ethylene is directly visualized from two-dimensional 1 H-1 H spin diffusion MAS NMR spectroscopy and further verified by computational density distributions. The 1 H MAS NMR spectroscopy provides an alternative for straightforwardly extracting the adsorption selectivity of ethane/ethylene mixture at 1.1∼9.6 bar in ZIFs, which is consistent with the IAST predictions.
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