A review on chitosan-based membranes for sustainable CO₂ separation applications: Mechanism, issues, and the way...

Effective carbon dioxide (CO₂) separation by nominal energy utilization is the factual attempt in the present era of energy scarcity and environmental calamity. In this perspective, the membrane- based gas separation technology is a budding endeavour owing to its cost -effectiveness, ease of operational maintenance and compact modular design. Among various membrane materials, bio-based polymers are of interest as they are abundant and can be obtained from renewable resources, and can also reduce our dependency on exhaustible fossil fuel-based sources. In this review, the structure-property relationship of chitosan and some of its film-forming derivatives has been critically studied for the first time in view of the fundamental properties required for gas separation applications. Various factors affecting the gas permeation performance of chitosan-based membranes have been highlighted along with prospects and propositions for the design of a few novel bio-based membranes based on the exhaustive analyses.