Rotaxane Pt^II-complexes: mechanical bonding for chemically robust luminophores and stimuli responsive behaviour

We report an approach to rotaxanes in which the metal ion of a cyclometallated Pt^II luminophore is embedded in the space created by the mechanical bond. Our results show that the interlocked ligand environment stabilises a normally labile Pt^II-triazole bond against displacement by competing ligands and that the crowded environment of the mechanical bond retards oxidation of the Pt^II centre, without perturbing the photophysical properties of the complex. When an additional pyridyl binding site is included in the axle, the luminescence of the Pt^II centre is quenched, an effect that can be selectively reversed by the binding of Ag^I. Our results suggest that readily available interlocked metal-based phosphors can be designed to be stimuli responsive and have advantages as stabilised triplet harvesting dopants for device applications.