Formation of Al₃₀ aggregates and its correlation to the coagulation effect

Al₃₀ is the polycation with the highest degree of polymerization and surface charge in the currently known structural aluminum species. It shows excellent coagulation performance in water treatment process, and has the characteristics of wide application range of pH and dosage. pH value is one of the most important factors affecting the aggregation and coagulation process of Al₃₀, but the influence of Al₃₀ aggregation reaction on its coagulation effect is still unclear. Therefore, this article reports the deprotonation and aggregation reaction of Al₃₀ by adjusting the basicity (B) of the solution, particularly to further understand the coagulation mechanism of Al₃₀ under different conditions. The results showed that in the base titration process, when B < 2.86 in 0.01 M Al₃₀ solution as Al_T (the concentration of total Al), deprotonation and preliminary aggregation mainly occurred; when B > 2.86, the size of Al₃₀ aggregates (Al₃₀agg) increased rapidly, forming gels and gradually transforming into Al(OH)₃. In this process, in addition to the reduction of electrostatic repulsion induced by Al₃₀ deprotonation, the oligomers generated by the partial dissociation of Al₃₀ also play the role of bridging-connection. Under the experimental titration conditions, the Al₃₀agg always maintained a positive zeta potential. In addition, Al₃₀ can deprotonate and aggregate at lower pH, which is an important reason for its unique coagulation characteristics. The larger structure size of Al₃₀ also made it easy to form branched aggregates, so that it can play an effective role in a wider dosage range without destabilization of colloids. This study gives an insight in the advancement of coagulants and promotes the industrial application and commercialization of functional coagulants based on polyaluminum.