Evaluation of static differential capacitance at the [C₄mim⁺][TFSA^-]/electrode interface using molecular dynamics...

Molecular dynamic (MD) simulations have been performed for 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide ([C₄mim⁺][TFSA^-]), an ionic liquid (IL), on a charged graphene electrode to achieve the quantitative analysis of the static differential capacitance using the electrochemical surface plasmon resonance (ESPR). The MD simulations have provided the surface charge density on the electrode and ionic distributions in the electric double layer, both of which are indispensable for the evaluation of static differential capacitance using ESPR but are difficult to be measured by experimental techniques. This approach has allowed the quantitative analysis and explanation of the SPR angle shift in ESPR. The major contribution to the SPR angle shift is found to be the change in ionic concentrations of the first ionic layer on the electrode, owing to higher polarizabilities of ions in the first ionic layer than those in the overlayers. Moreover, the ionic orientation on the electrode and ionic multilayer structure have also been investigated in detail. The butyl group of C₄mim⁺ in the first ionic layer is found to provide extra room for C₄mim⁺ in the second ionic layer but exclude TFSA^-, which affects the interval and regularity of ionic multilayers.