Ultrasound-boosted selectivity of CO in CO₂ electrochemical reduction

Among the possible products of CO₂ electrochemical reduction, CO plays a unique and vital role, which can be an ideal feedstock for further reduction to C₂₊ products, and also the important component of syngas that can be used as feedstock for value-added chemicals and fuels. However, it is still a challenge to tune the CO selectivity on Cu electrode. Here we newly construct an ultrasound-assisted electrochemical method for CO₂ reduction, which can tune the selectivity of CO₂ to CO from less than 10% to >80% at -1.18 V versus (vs.) reversible hydrogen electrode (RHE). The partial current density of CO production is significantly improved by 15 times. By in-situ Raman study, the dominating factor for the improved CO production is attributed to the accelerated desorption of *CO intermediate. This work provides a facile method to tune the product selectivity in CO₂ electrochemical reduction.