Stochastic thermodynamics of nanoscale friction

Developing the thermodynamics of nanoscale friction is needed in a wide range of tribological applications, where the key objective is to optimally control the energy dissipation. Here we show that modern stochastic thermodynamics allows us to interpret the measurements obtained by friction force microscopy, which is the standard tool for investigating the frictional properties of materials, in terms of basic thermodynamics concepts such as fluctuating work and entropy. We show that this allows the identification of the heat produced during the friction process as an unambiguous measure of thermodynamic irreversibility. We have applied this procedure to quantify the heat produced during the frictional sliding in a broad velocity range, and we observe velocity-dependent scaling behavior, which is useful for interpreting the experimental outcomes.