Tuning the shape and crystal phase of TiO₂ nanoparticles for catalysis

Synthesis of TiO₂ nanoparticles with tunable shape and crystal phase has attracted considerable attention for the design of highly efficient heterogeneous catalysts. Tailoring the shape of TiO₂, in the crystal phases of anatase, rutile, brookite and TiO₂(B), allows tuning of the atomic configurations on the dominantly exposed facets for maximizing the active sites and regulating the reaction route towards a specific channel for achieving high selectivity. Moreover, the shape and crystal phase of TiO₂ nanoparticles alter their interactions with metal species, which are commonly termed as strong metal-support interactions involving interfacial strain and charge transfer. On the other hand, metal particles, clusters and single atoms interact differently with TiO₂, because of the variation of the electronic structure, while the surface of TiO₂ determines the interfacial bonding via a geometric effect. The dynamic behavior of the metal-titania interfaces, driven by the chemisorption of the reactive molecules at elevated temperatures, also plays a decisive role in elaborating the structure-reactivity relationship.