Phase Engineering of Cesium Manganese Bromides Nanocrystals with Color-Tunable Emission

For display applications, it is highly desirable to obtain tunable red/green/blue emission. However, lead-free perovskite nanocrystals (NCs) generally exhibit broadband emission with poor color purity. Herein, we developed a unique phase transition strategy to engineer the emission color of lead-free cesium manganese bromides NCs and we can achieve a tunable red/green/blue emission with high color purity in these NCs. Such phase transition can be triggered by isopropanol: from one dimensional (1D) CsMnBr₃ NCs (red-color emission) to zero dimensional (0D) Cs₃ MnBr₅ NCs (green-color emission). Furthermore, in a humid environment both 1D CsMnBr₃ NCs and 0D Cs₃ MnBr₅ NCs can be transformed into 0D Cs₂ MnBr₄ ⋅2 H₂ O NCs (blue-color emission). Cs₂ MnBr₄ ⋅2 H₂ O NCs could inversely transform into the mixture of CsMnBr₃ and Cs₃ MnBr₅ phase during the thermal annealing dehydration step. Our work highlights the tunable optical properties in single component NCs via phase engineering and provides a new avenue for future endeavors in light-emitting devices.