Development of geopolymer waste form for immobilization of radioactive borate waste

Radioactive borate waste containing a high concentration of boron (B) is problematic to be solidified using cement because soluble borate such as boric acid hinders the hydration reaction. In this study, borate waste was used as a raw material for metakaolin-based geopolymer according to the characteristic that B replaces a part of Si. Geopolymers using KOH alkaline activator (K-geopolymers) showed higher compressive strength than geopolymers using NaOH alkaline activator (Na-geopolymer). In addition, the compressive strength increased proportionally to the Si/(Al+B) ratio regardless of the alkaline cation species. These variations in compressive strength might be due to the viscosity of the geopolymer mixture, atomic size of alkaline cations, and the increase in Si content. The characteristic analyses (XRD, FT-IR, and solid state ¹¹B MAS NMR) indicated that B was incorporated into the geopolymer structure. Thus, the K-geopolymer has a dense and homogeneous microstructure. In a semi-dynamic leaching test, less B leached from the geopolymers compared to the cement waste form. Consequently, borate waste can be solidified using metakaolin-based geopolymer, and the use of a KOH alkaline activator is advantageous in terms of mechanical property and structural durability.