Bimetallic MOFs-derived coral-like Ag-Mo₂C/C interwoven nanorods for amperometric detection of hydrogen peroxide

Coral-like Ag-Mo₂C/C-I and blocky Ag-Mo₂C/C-II composites were obtained from one-step in situ calcination of [Ag(HL)₃(Mo₈O₂₆)]_n·nH₂O [L: N-(pyridin-3-ylmethyl) pyridine-2-amine] under N₂/H₂ and N₂ atmospheres, respectively. The coral-like morphology of Ag-Mo₂C/C-I is composed of interwoven nanorods embedded with small particles, and the nano-aggregate of Ag-Mo₂C/C-II is formed by cross-linkage of irregular nanoparticles. The above composites are decorated on glassy carbon electrode (GCE) drop by drop to generate two enzyme-free electrochemical sensors (Ag-Mo₂C/C/GCE) for amperometric detection of H₂O₂. In particular, the coral-like Ag-Mo₂C/C-I/GCE sensor possesses rapid response (1.2 s), high sensitivity (466.2 μA·mM^-1·cm^-2), and low detection limit (25 nM) towards trace H₂O₂ and has wide linear range (0.08 μM~4.67 mM) and good stability. All these sensing performances are superior to Ag-Mo₂C/C-II/GCE, indicating that the calcining atmosphere has an important influence on microstructure and electrochemical properties. The excellent electrochemical H₂O₂ sensing performance of Ag-Mo₂C/C-I/GCE sensor is mainly attributed to the synergism of unique microstructure, platinum-like electron structure of Mo₂C, strong interaction between Mo and Ag, as well as the increased active sites and conductivity caused by co-doped Ag and carbon. Furthermore, this sensor has been successfully applied to the detection of H₂O₂ in human serum sample, contact lens solution, and commercial disinfector, demonstrating the potential in related fields of environment and biology. Graphical abstract.