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Updated: Nov 1, 2025

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
A rotational study of the 1:1 adduct of ethanol and 1,4-dioxane
Luca Evangelisti1, Gang Feng2, Walther Caminati3
1Dipartimento di Chimica "Giacomo Ciamician" dell'Università, Via S. Alberto 163, I-48123 Ravenna, Italy.
Abstract:
The pure rotational spectra of the 1:1 ethanol - 1,4-dioxane complex and its OD mono-deuterated species have been measured using pulsed-jet Fourier transform microwave spectroscopy. Conformational predictions for the plausible isomers of ethanol - 1,4-dioxane have been carried out considering the spatial orientation of gauche/trans ethanol with respect to the chair/boat and twisted conformations of 1,4-dioxane. Using Helium for the supersonic expansion, the microwave spectrum has been observed for the most stable structure. In the observed isomer, the two subunits are linked together by an OH⋯O hydrogen bond with gauche ethanol acting as proton donor to dioxane in the chair conformation. The non-covalent interactions have been characterized using different computational approaches. A small inverse Ubbelohde effect was observed after H → D isotopic substitution in the OH⋯O hydrogen bond.
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