Degradation of TBBPA by nZVI activated persulfate in soil systems

Tetrabromobisphenol A (TBBPA) greatly impacts on ecosystems and human health due to its high environmental toxicity and persistence. Persulfate (PS) advanced oxidation technology to remove organic pollutants in soils has received intense attention. In this study, nanoscale zero-valent iron (nZVI) was synthesized through the borohydride reduction method to explore its activating potential towards PS to accelerate the degradation of TBBPA in soils. The degradation behaviors of TBBPA in soils were investigated by batch experiments. The degradation efficiency of TBBPA (5 mg kg^-1) was 78.32% within 12 h under the following reaction conditions: 3 g kg^-1 nZVI, 25 mM PS, and pH 5.5 at 25 °C. Notably, PS can be used effectively, and the pH changed slightly in the reaction system. Oxidative degradation of TBBPA is favored at higher temperatures and lower pH values, while it is inhibited when the amount of catalyst increases significantly. The coexisting heavy metal ions such as Zn(II) and Ni(II) inhibit TBBPA degradation, while Cu(II) accelerates the degradation. Radical scavenging and electron spin resonance (ESR) tests further confirmed the generation of SO₄^·-, ·OH, and O₂^·- in nZVI activated PS. The intermediates identified by gas chromatograph-mass spectrometry analysis indicated that TBBPA via debromination and the cleavage between the isopropyl group and one of the benzene rings complete degradation. These findings provide new insight into the mechanism of nZVI activation of PS and will promote its application in the degradation of refractory organic compounds.