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Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
Published on: June 9, 2023
A review on metal-organic framework-derived anode materials for potassium-ion batteries
Qiongyi Xie1, Hong Ou1, Qingyun Yang1
1Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, Guangzhou Key Laboratory of Materials for Energy Conversion and Storage, School of Chemistry, South China Normal University, Guangzhou 510006, China. linxm@scnu.edu.cn likang5@m.scnu.edu.cn chenxinli@m.scnu.edu.cn maguozheng@m.scnu.edu.cn.
Abstract:
In recent years, metal-organic frameworks (MOFs) have been widely used in the field of electrochemical energy storage and conversion because of their excellent properties, such as high specific surface area, adjustable pore size, high porosity, structural diversity, and functional controllability. This paper reviews the applications of metal-organic framework-derived composites such as nitrogen-doped carbon, transition metal sulfides, transition metal selenides, transition metal phosphides and metal selenium compound modifications in potassium ion batteries (PIBs) as anode electrode materials. A variety of MOF-derived composites with different structures and morphologies based on several types of ligands, including 2-methylimidazole, aromatic carboxylic acids, and ferricyanide, have been discussed. Moreover, the current challenges faced by MOF-derived materials and possible countermeasures are proposed.
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